Issue |
Analusis
Volume 27, Number 10, December 1999
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Page(s) | 829 - 834 | |
Section | Original articles | |
DOI | https://doi.org/10.1051/analusis:1999150 |
DOI: 10.1051/analusis:1999150
Extraction preconcentration of platinum and ruthenium using high molecular weight amines prior to simultaneous determination by derivative spectrophotometry
M. Balcerzak and E. WyrzykowskaDepartment of Analytical Chemistry, Warsaw University of Technology, Noakowskiego 3, 00-664 Warsaw, Poland
(Received May 27, 1999; revised October 10, 1999; accepted November 2, 1999.)
Abstract
Platinum and ruthenium can be simultaneously extracted from hydrochloric acid solution by high molecular
weight amines (trioctylamine (TOA) or diantipyrylmethane (DAM) in 1,2-dichloroethane) after preliminary
conversion into the complexes with SnCl3- ligands. The determination of both metals in the presence
of each other in organic solutions of the formed ion-pairs can be accomplished by applying derivative
spectrophotometry. The values of the second derivative spectra at 395 nm and 437 nm, calculated with the
2-nd degree polynomial and 75 points correspond to the concentration of platinum associated with TOA and
DAM, respectively. The value of the second derivatives at 497 nm and 463 nm can make a basis of the
determination of ruthenium in the presence of platinum in the form of ion-pairs with TOA and DAM,
respectively. The use of TOA as extractant ensures higher precision and accuracy of the determination of
platinum and ruthenium by derivative spectrophotometry. RSD of the results of the determination of metals
in synthetic mixtures does not exceed 2.7 % and 3.2 % for platinum and ruthenium, respectively.
Key words: Platinum determination / ruthenium determination / extraction preconcentration / tin(II) chloride complexes / derivative spectrophotometry.
© EDP Sciences, Wiley-VCH 1999